Magnesium Sulphate (MgSO₄) – Detailed Properties
🔹 1. Basic Information
Property Details
Chemical Name Magnesium Sulphate
Chemical Formula MgSO₄
IUPAC Name Magnesium sulfate
Molar Mass 120.37 g/mol (anhydrous)
138.38 g/mol (monohydrate)
246.47 g/mol (heptahydrate)
CAS Number 7487-88-9 (anhydrous), 10034-99-8 (heptahydrate)
🔹 2. Physical Properties
Property Description
Appearance White crystalline solid or powder
Odor Odorless
Taste Bitter, saline
Density 2.66 g/cm³ (anhydrous)
1.68 g/cm³ (heptahydrate)
Melting Point ~1, 124°C (anhydrous)
Decomposes (hydrated forms lose water before melting)
Solubility in Water Highly soluble (71 g/L at 20°C for heptahydrate)
Solubility in Alcohol Slightly soluble
Color White or colorless crystals
Crystal System Orthorhombic (heptahydrate)
🔹 3. Chemical Properties
Property Description
pH of 5% Solution ~5.5 to 7.0 (near neutral)
Thermal Decomposition Hydrates lose water at low temperature:
- Heptahydrate → monohydrate → anhydrous
- Decomposes to magnesium oxide (MgO) and sulfur oxides at high heat
Stability Stable under normal storage conditions
Reactivity Reacts with carbonates to form magnesium carbonate; compatible with most neutral salts
Hygroscopicity Anhydrous form is hygroscopic; readily absorbs water to form hydrates
🔹 4. Hydrated Forms
Form Formula Common Name
Heptahydrate MgSO₄·7H₂O Epsom Salt
Monohydrate MgSO₄·H₂O Used in industrial drying
Anhydrous MgSO₄ Laboratory desiccant, fertilizer base
🔹 5. Applications & Uses
Field Application
Medicine / Healthcare - Used to treat magnesium deficiency (IV/IM)
- Laxative and saline purgative
- Anti-convulsant in eclampsia
- Muscle relaxant in emergency care
Agriculture - Soil additive for magnesium and sulfur
- Used in fertilizers for crops like tomatoes, potatoes, citrus
Personal Care / Cosmetics - Epsom salt baths (muscle relaxation)
- Skin softener and exfoliant
Chemical Industry - Catalyst support, pH stabilizer
- Used in dyeing and printing fabrics
Food Industry (E518) - Used as a firming agent and mineral supplement
Laboratories - Anhydrous MgSO₄ used as a drying agent for organic solvents
🔹 Biological Role
Aspect Description
Essential Mineral Supplies Mg²⁺, critical for enzyme function, nerve transmission, and muscle contraction
Human Use Treats low magnesium levels, preeclampsia, arrhythmia, asthma attacks (under supervision)
Plant Use Improves chlorophyll production and growth; prevents yellowing (magnesium deficiency)
🔹 Environmental Impact
Aspect Description
Biodegradability Not applicable (inorganic salt)
Toxicity Non-toxic to environment at normal concentrations
Aquatic Life Safe at low levels; high concentrations may affect balance
Soil Behavior Enhances plant growth; overuse can disrupt ion balance
🔹 Safety and Handling
Aspect Description
Toxicity Generally regarded as safe (GRAS); overdose can lead to magnesium poisoning (nausea, hypotension)
Inhalation Dust may irritate eyes and respiratory tract
Ingestion Safe in therapeutic doses; avoid large quantities without supervision
Storage Store in cool, dry, sealed containers; protect from moisture (anhydrous form)
✅ Summary Table
Property Heptahydrate (Epsom Salt) Anhydrous
Appearance White crystals White powder
Solubility High in water High in water
Uses Medical, agricultural, bath salt Drying agent, industrial
Safe Use Yes (with dosage limits) Yes